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dc.contributor.authorSENGE, MATHIASen
dc.date.accessioned2013-10-16T13:50:13Z
dc.date.available2013-10-16T13:50:13Z
dc.date.issued2011en
dc.date.submitted2011en
dc.identifier.citationFinnigan, E. M.; Rein, R.; Solladié, N.; Dahms, K.; Götz, D. C. G.; Bringmann, G.; Senge, M. O., Synthesis and ligand binding properties of triptycene-linked porphyrin arrays, Tetrahedron, 67, 2011, 1126 - 1134en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/67502
dc.descriptionPUBLISHEDen
dc.description.abstractMultiporphyrin arrays are a complex class of molecules with numerous potential applications in energy transfer, photomedicine and light harvesting. We have developed a facile/versatile route to a class of triptycene linked porphyrin arrays via both Suzuki and Sonogashira cross coupling methods which makes use of the rigid three-pronged orientation of triptycene to construct trimeric porphyrin arrays linked either in the meso or ?-position with various linker groups. In order to understand the properties of these potential antenna systems and probe their potential applications, the coordination behavior of zinc(II) derivatives with mono- and bidentate N-donor ligands was investigated. Depending on ligand concentration, both one- and two-point binding was observed with a bidentate ligand. Also/In addition, different cavity sizes, obtained by the use of different linker groups, resulted in differences in the binding properties of each trimeric system.en
dc.description.sponsorshipThis work was generously supported by grants from Science Foundation Ireland (SFI 07/RFP/CHEF232 and SFI P.I. 09/IN.1/B2650). We are grateful to Rebecca Duke and Prof. Thorri Gunnlaugsson for assistance with the Specfit analysis.en
dc.format.extent1126en
dc.format.extent1134en
dc.language.isoenen
dc.relation.ispartofseriesTetrahedronen
dc.relation.ispartofseries67en
dc.rightsYen
dc.subject.otherPorphyrins
dc.titleSynthesis and ligand binding properties of triptycene-linked porphyrin arraysen
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengemen
dc.identifier.rssinternalid77993en
dc.rights.ecaccessrightsOpenAccess
dc.contributor.sponsorGrantNumberFP/CHEF232 anden
dc.contributor.sponsorGrantNumber09/IN.1/B2650en


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