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dc.contributor.authorKOPF, ILONA
dc.date.accessioned2011-06-08T11:43:35Z
dc.date.available2011-06-08T11:43:35Z
dc.date.issued2010
dc.date.submitted2010en
dc.identifier.citationFilimon, M, Kopf, I, Ballout, F, Schmidt, DA, Brundermann, E, Ruhe, J, Santer, S, Havenith, M, Smart polymer surfaces: mapping chemical landscapes on the nanometre scale, Soft Matter, 6, 2010, 3764-3768en
dc.identifier.otherY
dc.identifier.urihttp://hdl.handle.net/2262/56529
dc.descriptionPUBLISHEDen
dc.description.abstractWe show that Scattering Infrared Near-field Microscopy (SNIM) allows chemical mapping of polymer monolayers that can serve as designed nanostructured surfaces with specific surface chemistry properties on a nm scale. Using s-SNIM a minimum volume of 100 nm 100 nm 15 nm is sufficient for a recording of a ``chemical?? IR signature which corresponds to an enhancement of at least four orders of magnitudes compared to conventional FT-IR microscopy. We could prove that even in cases where it is essentially difficult to distinguish between distinct polymer compositions based solely on topography, nanophase separated polymers can be clearly distinguished according to their characteristic near-field IR response.en
dc.description.sponsorshipM. Filimon acknowledges financial support by Marie Curie Early Stage Research Training, in the framework of the project INTCHEM (MEST-CT-2005-020681). We acknowledge financial support under grant BMBF 05KS7PC2 for innovativeinstrumentation of the synchrotron ANKA and by the Deutsche Forschungsgemeinschaft (HA2394/12-1).en
dc.format.extent3764-3768en
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofseriesSoft Matter;
dc.relation.ispartofseries6;
dc.rightsYen
dc.subjectChemistryen
dc.subjectnanophase separated polymersen
dc.titleSmart polymer surfaces: mapping chemical landscapes on the nanometre scaleen
dc.typeJournal Articleen
dc.contributor.sponsorMarie Curieen
dc.contributor.sponsorINTCHEMen
dc.contributor.sponsorDeutsche Forschungsgemeinschaft (DFG)en
dc.contributor.sponsorBMBFen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/kopfi
dc.identifier.rssinternalid71723
dc.contributor.sponsorGrantNumberMEST-CT-2005-020681en
dc.contributor.sponsorGrantNumberMEST-CT-2005-020681en
dc.contributor.sponsorGrantNumberHA2394/12-1en
dc.contributor.sponsorGrantNumber05KS7PC2en
dc.identifier.rssurihttp://dx.doi.org/10.1039/C0SM00098Aen


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