Show simple item record

dc.contributor.authorSENGE, MATHIASen
dc.date.accessioned2011-06-02T13:48:31Z
dc.date.available2011-06-02T13:48:31Z
dc.date.issued2011en
dc.date.submitted2011en
dc.identifier.citationSenge MO, Dahms K., {rac-5-[Meth-oxy(phen-yl)meth-yl]-10,20-diphenyl-porphyrinato}nickel(II), Acta Crystallographica Section E, 67, 2, 2011, m265en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/56342
dc.descriptionPUBLISHEDen
dc.description.abstractThe title compound, [Ni(C40H28N4O)], was obtained from a Grignard reaction of the respective formyl-porphyrin to yield {5-[hy-droxy(phen-yl)meth-yl]-10,20-diphenyl-porphyrinato}nickel(II), followed by crystallization from methyl-ene chloride/methanol. The mol-ecule exhibits a ruffled macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (?24) of 0.26?? and an average Ni?N bond length of 1.931?(2)??. In line with the asymmetrical substituent pattern, the degree of distortion is slightly larger at point of attachment of the meth-oxy(phen-yl)methyl residue than at the unsubstituted meso position. The meth-oxy group attached to the chiral C atom is disordered in a 0.534?(4):0.466?(4) ratio.en
dc.format.extentm265en
dc.language.isoenen
dc.relation.ispartofseriesActa Crystallographica Section Een
dc.relation.ispartofseries67en
dc.relation.ispartofseries2en
dc.rightsYen
dc.subjectPhysical chemistryen
dc.subjectPorphyrinen
dc.title{rac-5-[Meth-oxy(phen-yl)meth-yl]-10,20-diphenyl-porphyrinato}nickel(II)en
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengemen
dc.identifier.rssinternalid73508en
dc.identifier.doihttp://dx.doi.org/10.1107/S1600536811002960en
dc.contributor.sponsorGrantNumber09/IN.1/B2650en
dc.subject.TCDThemeNanoscience & Materialsen
dc.identifier.rssuri002960en


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record