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dc.contributor.authorVIJ, JAGDISH KUMAR
dc.date.accessioned2010-07-13T16:22:00Z
dc.date.available2010-07-13T16:22:00Z
dc.date.issued1993
dc.date.submitted1993en
dc.identifier.citationVIJ, JK Yu P. Kalmykov, On the internal field correction in far ]infrared absorption of highly polar molecules in neat liquids and dilute solutions, Journal of Chemical Physics, 99, 4, 1993, 2506 - 2510en
dc.identifier.otherY
dc.identifier.urihttp://hdl.handle.net/2262/40304
dc.descriptionPUBLISHEDen
dc.description.abstractFar-infrared absorption spectra for liquid acetone, methylene chloride, acetonitrile, methyl iodide, and their dilute solutions in cyclohexane at 20?C are measured by molecular laser spectrometer. Measurements of dielectric loss of polar liquids and solutions in the frequency range 2-300 GHz are made using a number of different techniques. These two sets of measurements are combined with those made using a Fourier transform spectrometer in order to cover the frequency range up to 250 cm -I and total integrated absorption intensities are calculated. It is shown that the discrepancy between experimental integrated absorption and the theoretical results given by Gordon's sum rule with the Polo-Wilson internal field factor can be explained in the context of Bossis' theory. This theory gives a better agreement with the experimental integrated absorption intensity for these liquids.en
dc.description.sponsorshipOne of the authors (JKV) is grateful to the late Professor Dr. F. Hufnagel for useful discussions and for allowing access to the experimental facilities.en
dc.format.extent2506en
dc.format.extent2510en
dc.language.isoenen
dc.publisherAmerican Institute of Physicsen
dc.relation.ispartofseriesJournal of Chemical Physics;
dc.relation.ispartofseries99;
dc.relation.ispartofseries4;
dc.rightsYen
dc.subjectInfrared spectraen
dc.titleOn the internal field correction in far ]infrared absorption of highly polar molecules in neat liquids and dilute solutionsen
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/jvij
dc.identifier.rssinternalid24434


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