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dc.contributor.authorSENGE, MATHIAS
dc.date.accessioned2010-06-15T11:32:41Z
dc.date.available2010-06-15T11:32:41Z
dc.date.issued1996
dc.date.submitted1996en
dc.identifier.citationM. O. Senge, Bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N",N'")-iron(III) Perchlorate Bis(methanol) Solvate, [Fe(III)oep(HOCH3)2][ClO4].2CH3OH, Acta Crystallographica C, 52, 2, 1996, 302 - 305en
dc.identifier.otherY
dc.identifier.urihttp://hdl.handle.net/2262/40135
dc.descriptionPUBLISHEDen
dc.description.abstractSimple treatment of [FeIII(oep)Cl] (where oep is octaethylporphyrin) with dilute perchloric acid leads to facile preparation of the title compound, [Fe(C36H44N4)(CH4O)2](ClO4).2CH4O. The structure consists of discrete [Fe(oep)(HOCH3)2]+ cations, perchlorate anions and methanol molecules of solvation, which are connected by hydrogen bonds in an infinite network. The Fe atom is located in the plane of the N atoms and is coordinated by two methanol O atoms in the axial position, with an average Fe-N distance of 2.026 (3) ? and Fe-O bond lengths of 2.159 (3) ?.en
dc.description.sponsorshipThis work was supported by grants from the Deutsche Forschungsgemeinschaft (Se543/2-1 and/2-2) and the Fonds der Chemischen Industrie.en
dc.format.extent302en
dc.format.extent305en
dc.language.isoenen
dc.publisherInternational Union of Crystallographyen
dc.relation.ispartofseriesActa Crystallographica C;
dc.relation.ispartofseries52;
dc.relation.ispartofseries2;
dc.rightsYen
dc.subjectChemistryen
dc.subject[Fe(C36H44N4)(CH4O)2](ClO4).2CH4Oen
dc.titleBis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N",N'")-iron(III) Perchlorate Bis(methanol) Solvate, [Fe(III)oep(HOCH3)2][ClO4].2CH3OHen
dc.typeJournal Articleen
dc.contributor.sponsorDeutsche Forschungsgemeinschaft (DFG)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengem
dc.identifier.rssinternalid29220
dc.identifier.rssurihttp://dx.doi.org/10.1107/S0108270195006068en


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