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dc.contributor.authorCOFFEY, WILLIAM THOMAS
dc.contributor.authorKALYMYKOV, YURI PETROVICH
dc.date.accessioned2009-06-17T11:56:16Z
dc.date.available2009-06-17T11:56:16Z
dc.date.issued2007
dc.date.submitted2007en
dc.identifier.citationYu.P. Kalmykov and S.V. Titov, Anisotropic rotational diffusion and transient nonlinear responses of rigid polar macromolecules in a strong external electric field in Journal of Chemical Physics, 126, 17, (2007), art no. 174903en
dc.identifier.otherY
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/30550
dc.descriptionPUBLISHEDen
dc.description.abstractNonlinear transient responses of polar polarizable particles (macromolecules) diluted in a nonpolar solvent to a sudden change in magnitude of a strong external dc field are evaluated using the anisotropic noninertial rotational diffusion model. The relaxation functions and relaxation times appropriate to the transient dynamic Kerr effect and nonlinear dielectric relaxation are calculated by solving the infinite hierarchy of differential-recurrence equations for statistical moments (ensemble averages of the Wigner D functions). The calculations involve matrix continued fractions, which ultimately yield the exact solution of the infinite hierarchy of differential-recurrence relations for the first- and second-order transient responses.en
dc.description.sponsorshipThe authors thank Professor W. T. Coffey for stimulating discussions and useful comments.en
dc.format.extentart no. 174903en
dc.format.extent543331 bytes
dc.format.mimetypeapplication/pdf
dc.language.isoenen
dc.publisherAmerican Institute of Physicsen
dc.relation.ispartofseriesJournal of Chemical Physicsen
dc.relation.ispartofseries126en
dc.relation.ispartofseries17en
dc.rightsYen
dc.subjectElectronic & Electrical Engineeringen
dc.titleAnisotropic rotational diffusion and transient nonlinear responses of rigid polar macromolecules in a strong external electric fielden
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/wcoffey
dc.identifier.rssinternalid45207


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