Browsing Chemistry (Theses and Dissertations) by Subject "Reactive Intermediates"
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High-valent nickel complexes supported by pyridinedicarboxamidate ligands in hydrocarbon oxidation reactions (Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2017)High-valent M=O and M-O-X complexes are hypothesised to be potent oxidising intermediates both in enzymatic and small-molecule catalysis. In contrast to those from groups 6-8, oxidants that contain late transition metals ...